You could send some of that /27 across OpenVPN to the other site if the /27 is routed to you.
If the interface is a /27 that's going to be much more difficult.
I have no where close to the amount of into about what your trying to do... I suggest you consult
https://docs.netgate.com/pfsense/en/latest/firewall/virtual-ip-address-feature-comparison.html
But yes normally that type is what you would use.