@viragomann I've removed the static routes and restarted things.
I have this setup in the OpenVPN config for both interfaces.
6545aeb1-6782-4570-ab9c-fe46ad927de3-{81ED3D47-5D8F-475C-9513-5A0C4810782C}.png
The bit I was missing was the IPv4 Tunnel Network IP, I just put that in and everything seems to be working!
I'm now going to back all this up and then grab a copy of this session as notes for if I ever need to add a third VPN.
Thanks very much for the help debugging this, it was more complex than I thought, but in the end it all makes sense I think. I'll re-read it all in the morning, it will probably have sunk in by then.