Sure.. But that would have nothing to do with the camera's normal IPv4 address.. You stated "move this traffic from say 192.168.x.0/24" like you were going to change the devices IPv4 address to a multicast address.. You wouldn't do that - the device still needs it normal IPv4 address.
What multicast address space you want to use for multicast traffic has nothing to do with that.
As to anything you would do on pfsense.. Nothing.. devices on the same L2 talking multicast to each other would have nothing to do with pfsense.
Also not sure why you would use anything in 225, that is reserved multicast space.. If want to create multicast groups, does your switch(es) support IGMP snooping, or wireless?
I woulds assume your camera's talking multicast anyway.. There is no reason to specify which group they are on (via address) unless you have multiple multicast streams on this L2 network, and your wanting to have your switching infrastructure limit which devices see what streams by allowing the devices to join a specific group..