@alexhen
You cannot schedule NAT rules.
You have scheduled the associated firewall rules though, but even if these rules are disabled, the NAT rules are still active and do what they meant to do and the first one wins.
Not really sure what to try to achieve with this idea. If you just have two internal servers listening on port 80 set up HAproxy. Doing so you can also let HAproxy do the lets encrypt stuff.
Also you can run a proxy on one of the backends themself.