How are the two networks connected now? You can't send traffic through a gateway in another subnet like that. You need some kind of transit network. For example, if it's a dedicated circuit, you'd have that plugged into an additional NIC (or VLAN) on both pfSense firewalls, and then you'd have some other unrelated subnet to talk between them there. Then you use the address in that subnet as a gateway to reach the other.
If you have your LANs plugged together so they're all in the same Layer 2/flat network that is going to be a huge mess.