You need to create the 2 network interfaces.. be it you want to make 1 wan and 1 lan in pfsense. Or 2 lan side interfaces.
Issue you run into with using 1 as wan in pfsense for your 2 networks would be pfsense would be default nat..
Your better off doing 1 of these networks on lan, and then creating another lan side network, opt1 be it physical interface via vnic and vswitch in your VM software or a vlan is up to you.. I would do native if me, less complicated.. vlans on vm software can be a bit tricky
So on this new opt1 network, just create the network IP range you want to use... And then create firewall rule that allows access to your lan.