Well, if you haven't set it up very strangely, the routes should already be there. But to be sure, you can check Diagnostics -> Routes. You can also try to ping a host on the other network. If you don't get something like "Destination net unreachable", chances are good that your routes are fine.
Most likely you need to add/adapt some firewall rules. Probably you have some firewall rules that restrict access between your LANs before the "allow to any" rule that allows Internet traffic, or the "allow to any" rule excludes your local networks?
I haven't completely understood your SERV setup. As far as I understand, webmail.ORGNAME.co.uk has a public IP so it is accessible from Internet? How do you map that to your private IP addresses?