Huh? No a router can not have the same networks or overlapping networks on multiple interfaces, ie its wan and lan..
But if the /29 is routed to you this would never be the case since your wan would be the transit network and wouldn't overlap with your routed /29
This has zero to do specific with pfsense - and is just basic 101 routing.
Here lets do an example...
isp .1 --- 1.2.3.0/30 --- .2 wan pfsense opt .1 --- 4.5.6.0/29 --- devices .2, .3, .4 etc..
And sure pfsense could also have lan network in 192.168.1.0/24
Now your isp routes 4.5.6.0/29 to your 1.2.3.2 address.