@Snailkhan
By default the primary interface IP is used for communication with other devices.
If you want pfSense to use the CARP VIP you have to add an outbound NAT rule to LAN or the respective interface and set the CARP VIP as translation address.
However, don't do this for any traffic! It would lead into issues with services running on both nodes, e.g. DHCP.
So limit the destination (IP and port) to the domain controller or whatever you need it for.