Reading your diagram that the isp gave you, it looks like a normal static ipv6 configuration.
Basically you configure the ::2 of the /126 prefix on the pfSense wan interface. You then create a gateway to the ::1 address of the /126 subnet. Normally the isp router will reply for ndp requests for this address.
You can configure the 1st /64 prefix on the lan interface. Your isp will just forward the /64 networks to the ::2 address of your /126 subnet.
This really is a basic static config as long as both the isp and pfsense reply to ndp requests. Which i think they will.
If you have any questions or want me to review your configuration i can verify it remotely.