I have fixed my weird web interface time outs now. It seems just one was being particularly slow, the BACKUP CARP device, the MASTER was OK.
I took the compact flash card out of the BACKUP ALIX board and put it in a third board of the exact same spec, still slow. I then wiped and re-flashed the card, placed it back into it's original BACKUP ALIX board, and restored the config from which I had backed up to my laptop. Now its as fast as the MASTER and everything is fine, so perhaps it was a bad flash.
That may seem a bit obvious, and a waist of time posting here, but we have 40+ ALIX & WRAP boards, this has happened before.
Hopefully that will help someone else!
Cheers,
JamesB.