First what are you trying to block?
Second In target Categories make two lists see pic.
in the Categories make what you want to block and same thing on the white list what you do not want to block
in the group ACL make another 2 lists see pic
in the ACL edit on which IP will be blocked and edit the target rules for that list see pic
then click save then apply the settings then delete the cache and try out if it blocks
Remember it will block http sites not https sites. Example: typing www.facebook.com it will be http but going to google then typing facebook it will show https. Now these days sites are using https more :-[ but the most basic or porn sites are usally http
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