Just installed aprwatch package.
Settings used :
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Had to stop it an hour later : my (self hosted) mail box received hundreds of mails from arpwatch.
This means :
My Sys > Adv > Notifications has been set up correctly ;)
"arpwatch" sends mail using the pfSense mail notational system .... and it does as advertised.
Btw : take note of the warning :
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I know what 'gmail' might do when you bombard it with pretty identical mails (from the same IP). It will do what it should do : it will discard and block them ....
Upfront, you should white list (make the sender mail a contact, etc).
gmail is nice to be sued as a things-go-bad-notifier, but do not spam them.